| (a) | Heat is a way of transferring energy. |
| (b) | Heat is not a property of the system, whereas temperature is a property of the system. |
| (c) | Reactions that are accompanied by the evolution of heat are called endothermic reactions. |
| (d) | Those reactions in which heat is absorbed are known as exothermic reactions. |
| Column I (Reactions) | Column II (Enthalpy) | ||
| (A) | \(\small{CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O}\) | (i) | \(\Delta _{sol}H^o\) |
| (B) | \( H_{2(g)} \rightarrow 2H_{(g)}\) | (ii) | \(\Delta _{lattice}H^o\) |
| (C) | \(NaCl_{(s)} \rightarrow Na^+_{(g)} + Cl^-_{(g)} \) | (iii) | \(\Delta _{c}H^o\) |
| (D) | \(NaCl_{(s)} \rightarrow Na^+_{(aq)} + Cl^-_{(aq)} \) | (iv) | \(\Delta _{bond}H^o\) |
The enthalpy change for the reaction is called
1. Enthalpy of formation
2. Enthalpy of vaporisation
3. Enthalpy of sublimation
4. Enthalpy of combustion
| 1. | 120.9 | 2. | 241.82 |
| 3. | 18 | 4. | 100 |

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The standard heat of combustion of carbon (graphite) to CO₂ is –393.5 kJ mol⁻¹. Calculate the heat released when 15.84 g of CO₂ is formed from carbon (graphite) and oxygen gas:
1. 212.49 kJThe enthalpy of vaporisation of a liquid is 30 kJ mol–1 and entropy of vaporisation is 75 J mol–1 k–1. What is the boiling point of the liquid at 1 atm?
| 1. | 50 K | 2. | 400 K |
| 3. | 450 K | 4. | 600 K |
The standard enthalpies of formation of diamond and fullerene are 1.90 kJ mol⁻¹ and 38.1 kJ mol⁻¹, respectively. Calculate the enthalpy change for the conversion of diamond to fullerene:
| 1. | –222 kcal | 2. | –88 kcal |
| 3. | –111 kcal | 4. | –79 kcal |