The enolic form of ethyl acetoacetate is given below:

 

The number of σ and π bonds in the enolic form are respectively:

1. 18 sigma bonds and 2 pi-bonds
2. 16 sigma bonds and 1 pi-bond
3. 9 sigma bonds and 2 pi-bonds
4. 9 sigma bonds and 1 pi-bond

Which structure corresponds to the IUPAC name 3-Ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid?

1.		2.
3.		4.

Two possible stereo-structures of CH₃CHOH.COOH, that are optically active, called:

Which of the following statements is not correct for a nucleophile?

1. Nucleophile is a Lewis acid.
2. Ammonia is a nucleophile.
3. Nucleophiles attack low electron density sites.
4. Nucleophiles are not electron-seeking.

In Kjeldahl’s method for estimation of nitrogen present in the soil sample, ammonia evolved from 0.75g of sample neutralized 10ml of 1M H₂SO₄. The percentage of nitrogen in the soil is:

Hyperconjugation occurs among the following compounds:

The correct statement about the S_N1 reaction is:

In which of the following compounds, the C—Cl bond ionization shall give the most stable carbonium ion?

1.		2.
3.		4.

In Duma's method for estimation of nitrogen, 0.25 g of an organic compound gave 40 mL of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension at 300 K is 25 mm, the percentage of nitrogen in the compound is: