Q. No.The bonding present in nitrogen molecules is:
1. \(p\pi-p\pi\)
2. \(p\pi-d\pi\)
3. \(d\pi-d\pi\)
4. Only sigma bond
| Assertion (A): | R3P = O exists but R3N = O does not (R = alkyl group). |
| Reason (R): | Nitrogen doesn't have d orbitals. |
| 1. | (A) is true and (R) is the correct explanation of (A). |
| 2. | (A) is true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false |
The correct increasing order of basic strength of hydrides:
1. BiH3 \(\simeq \) SbH3 < AsH3 < PH3 < NH3
2. BiH3 > NH3 > PH3 > SbH3 > AsH3
3. SbH3 < AsH3 < PH3 < NH3 < BiH3
4. AsH3 > NH3 > PH3 > SbH3 > BiH3
The disproportionation reaction of is as follows:
X and Y in the above reaction are:
1. H3PO2, HPO2
2. H3PO4, PH3
3. H2PO6, PO3
4. None of the above.
Which of the following is true about reactivity of group 15 elements?
1. Stability of their hydrides increases down the group.
2. Higher oxides are acidic in nature.
3. All elements form pentahalides.
4. They do not react with metals.
| Assertion (A) | Nitrogen exists as a diatomic molecule and phosphorus as P4. |
| Reason (R) | Phosphorus is smaller in size, so it can form P4. |
| 1. | (A) is true and (R) is the correct explanation of (A). |
| 2. | (A) is true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false |
| Assertion (A): | Phosphorous (V) has a tendency to only gain electrons as it is in its highest oxidation state |
| Reason (R): | PCl5 can act as an oxidizing as well as a reducing agent. |
| 1. | (A) is true and (R) is the correct explanation of (A). |
| 2. | (A) is true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false |
The correct order of bond dissociation energy of halogens is-
1. F2 < Cl2 < Br2 < I2
2. I2 > Br2 > F2 > Cl2
3. Cl2 > Br2 < F2 > I2
4. I2 < F2 < Br2 < Cl2
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