| 1. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3 \) | 2. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl} \) |
| 3. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \) | 4. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\) |
| Statement I: | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex. |
| Statement II: | Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligand but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligands. |
The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes
CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is:
| 1. | 3AgCl, 1AgCl, 2AgCl | 2. | 3AgCl, 2AgCl, 1AgCl |
| 3. | 2AgCl, 3AgCl, 1AgCl | 4. | 1AgCl, 3AgCl, 2AgCl |
The sum of the coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl is:
| 1. | Nine (9) | 2. | Six (6) |
| 3. | Seven (7) | 4. | Eight (8) |
The IUPAC name of complex ion, [Fe(CN)6]3- is:
| 1. | Hexacyanoiron(III) ion | 2. | Hexacyanitoferrate(III) ion |
| 3. | Tricynoferrate(III) ion | 4. | Hexacyanidoferrate(III) ion |
Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:
| 1. | CoCl3. 3NH3 | 2. | CoCl3. 4NH3 |
| 3. | CoCl3. 5NH3 | 4. | CoCl3. 6NH3 |
A complex ion among the following can absorb visible light is:
(At. no. Zn = 30, Sc = 21, Ti = 22, Cr = 24)
1. [Sc(H2O)3(NH3)3]3+
2. [Ti(en)2 (NH3)2]4+
3. [Cr(NH3)6]3+
4. [Zn(NH3)6]2+