Match the following:
Column-I (Complexes) Column-II (Metals)
A. Vitamin \(\text{B}_{12}\) (p) \(\text{Ti}\)
B. Wilkinson catalyst (q) \(\text{Co}\)
C. Ziegler-Natta catalyst (r) \(\text{Fe}\)
D. Haemoglobin (s) \(\text{Rh}\)
1. A(q), B(s), C(p), D(r)
2. A(s), B(q), C(r), D(p)
3. A(q), B(p), C(r), D(s)
4. A(q), B(r), C(p), D(s)
Subtopic:  Organometallic Complexes & their Uses |
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Level 1: 80%+
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X: No. of Bridge Bonds present in compound Mn2(CO)10.
Y: No. of Bridge Bonds present in compound W(CO)6
The sum of (X+Y) is: 
1. 1
2. 4
3. 0
4. 2
Subtopic:  Organometallic Complexes & their Uses |
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The cation that exhibits a bright red color when reacting with dimethyl glyoxime is:

1. Cu2+
2. Ni2+
3. Zn2+
4. Co2+
Subtopic:  Organometallic Complexes & their Uses |
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The structure of Mn2O has

X: Number of Mn-Mn bonds.
Y: Number of Mn- O- Mn bonds.

The value of (X+Y) is:

1. 0 
2. 1
3. 5
4. 3 
Subtopic:  Organometallic Complexes & their Uses |
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The complex that is utilized for inhibiting the proliferation of cancer cells is:
1. Cis-platin
2. EDTA
3. Cobalt
4. Ethanol-1,2-diamine
Subtopic:  Organometallic Complexes & their Uses |
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In the structure of Co2(CO)8, X is the number of Co-Co bonds and Y is the number
of Co-CO terminal bonds. The value of X + Y is:
1. 8 2. 6
3. 10 4. 7
Subtopic:  Organometallic Complexes & their Uses |
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Level 3: 35%-60%
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The stepwise formation of [Cu(NH3)4]2+ is given below

Cu2++NH3K1[Cu(NH3)]2+[Cu(NH3)]2++NH3K2[Cu(NH3)3]2+[Cu(NH3)2]2++NH3K3[Cu(NH3)3]2+[Cu(NH3)3]2++NH3K4[Cu(NH3)4]2+

The value of stability constants K1, K2, K3 and K are 104,1.58×103,5×102 and 102 respectively. The overall equilibrium constants for the dissociation of [Cu(NH3)4]2+ is x × 10–12. The value of x is ________.

(Rounded off to the nearest integer)

1. 2 2. 4
3. 3 4. 1
Subtopic:  Organometallic Complexes & their Uses |
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Number of bridging CO ligands in [Mn2(CO)10] is:

1. 2 2. 0
3. 4 4. 1
Subtopic:  Organometallic Complexes & their Uses |
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Match List-I with List-II:
List-I List-II
(a) Chlorophyll (i) Ruthenium
(b) Vitamin \(\text B_{12}\) (ii) Platinum
(c) Anticancer drug (iii) Cobalt
(d) Grubbs catalyst (iv) Magnesium
1. (a)–(iv), (b)–(iii), (c)–(i), (d)–(ii)
2. (a)–(iv), (b)–(iii), (c)–(ii), (d)–(i)
3. (a)–(iii), (b)–(ii), (c)–(iv), (d)–(i)
4. (a)–(iv), (b)–(ii), (c)–(iii), (d)–(i)
Subtopic:  Organometallic Complexes & their Uses |
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Which of the following compounds inhibits the growth of tumors?

1. cis-[Pd(Cl)2(NH3)2]

2. trans-[Pd(Cl)2(NH3)2]

3. cis-[Pt(Cl)2(NH3)2]

4. trans-[Pt(Cl)2(NH3)2]

Subtopic:  Organometallic Complexes & their Uses |
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