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Q. No.Consider the given two statements:
| Assertion(A): | \(\mathrm{E^0_{cell}}\) = 0 for a chloride ion concentration cell. |
| Reason(R): | For this concentration cell, the equation is given by: \(E_{\mathrm{cell}}=\frac{R T}{n F} \ln \left(\frac{\left[\mathrm{Cl}^{-}\right]_{\mathrm{LHS}}}{\left[\mathrm{Cl}^{-}\right]_{\mathrm{RHS}}}\right) \) |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A) |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Subtopic: Nernst Equation |
From NCERT
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For the following cell with hydrogen electrodes at two different pressures p1 and p2
Pt(H2) | H+(aq) |Pt (H2)
p1 1M p2
emf is given by:
1. \(\frac{R T}{F} \log _{e} \frac{P_{1}}{p_{2}}\)
2. \(\frac{R T}{2F} \log _{e} \frac{P_{1}}{p_{2}}\)
3. \(\frac{R T}{F} \log _{e} \frac{P_{2}}{p_{1}}\)
4. \(\frac{R T}{2F} \log _{e} \frac{P_{2}}{p_{1}}\)
Subtopic: Nernst Equation |
From NCERT
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The reduction potential of hydrogen half-cell will be negative if:
1. P(H2) = 1atm and [H+] = 2.0 M
2. P(H2) = 1 atm and [H+] = 1.0 M
3. P(H2) = 2 atm and [H+] = 1.0 M
4. P(H2) = 2 atm and [H+] = 2.0 M
Subtopic: Nernst Equation | Relation between Emf, G, Kc & pH |
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From NCERT
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