For a salt XY, which is a strong electrolyte, the plot of \(\Lambda_m\) versus \(\sqrt{c}\) has a slope of -90.0 S cm² mol-3/2 L1/2 at 298 K. At 0.01 M concentration of XY, the value of \(\Lambda_m\) is 145.0 S cm² mol-1. The limiting molar conductivity of Yion (\(\lambda_{Y-}^0\), in S cm² mol-1) at 298 K will be:
(Given: \(\lambda_{X+}^0\) = 74.0 S cm² mol-1)
1. 76.0
2. 80.0
3. 100.0
4. 90.0
Subtopic:  Conductance & Conductivity |
Level 3: 35%-60%
NEET - 2026
Please attempt this question first.
Hints
Please attempt this question first.

If the molar conductivity \(\left(\Lambda_{\mathrm{m}}\right)\) of a \(0.050 ~\text{mol}~ \text{L}^{-1}\) solution of a monobasic weak acid is \(90 ~\text{S} ~\text{cm}^2 ~\text{mol}^{-1}\), then its degree of dissociation will be: [Assume \(\Lambda_{+}^0=349.6~ \mathrm{S ~cm}^2 \mathrm{~mol}^{-1}\) and \(\mathrm{\Lambda}_{-}^{\circ}=50.4 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1} \)]
1. \( 0.225 \) 2. \( 0.215 \)
3. \(0.115 \) 4. \(0.125\)
Subtopic:  Conductance & Conductivity |
 61%
Level 2: 60%+
NEET - 2025
Please attempt this question first.
Hints
Please attempt this question first.

The conductivity of centimolar solution of KCl at 25°C is 0.0210 ohm–1 cm–1 and the resistance of the cell containing the solution at 25°C is 60 ohm. The value of the cell constant is: 
1. 3.34 cm–1 2. 1.34 cm–1
3. 3.28 cm–1 4. 1.26 cm–1
Subtopic:  Conductance & Conductivity |
 82%
Level 1: 80%+
NEET - 2023
Hints

advertisementadvertisement

The molar conductance of an electrolyte increases with dilution according to the equation: 
\(\Lambda_{\mathrm{m}}=\Lambda_{\mathrm{m}}^{\circ}-\mathrm{A} \sqrt{\mathrm{c}} \)
Consider the following four statements:
A: This equation applies to both strong and weak electrolytes
B: The value of the constant A depends upon the nature of the solvent 
C: The value of constant A is the same for both \(BaCl_2\) and \(MgSO_4\)
D: The value of constant A is the same for both \(BaCl_2\) and \(Mg(OH)_2\)

Which of the above statements are correct? 
1. (A) and (B) only  2. (A), (B), and (C) only 
3. (B) and (C) only  4. (B) and (D) only 
Subtopic:  Conductance & Conductivity |
 58%
Level 3: 35%-60%
NEET - 2023
Hints

The molar conductance of a solution, given its conductivity (0.248 S m–1) and concentration (0.2 mol m–3) is:
1. 0.124 S cm2 mol–1 2. 1.24 S m2 mol–1
3. 124 S cm2 mol–1 4. 124 S m2 mol–1
Subtopic:  Conductance & Conductivity |
Level 3: 35%-60%
NEET - 2023
Hints

\(\land^o_m\) for NaCl, HCl and \(\mathrm{CH_3COONa }\) are 126.4, 425.9, and 91.05 S cm2 mol–1 respectively. If the conductivity of 0.001028 mol L–1 acetic acid solution is \(4.95 \times 10^{-5} S ~cm^{-1} \), the degree of dissociation of the acetic acid solution is:
1. 0.01233
2. 1.00
3. 0.1233
4. 1.233

Subtopic:  Conductance & Conductivity |
 59%
Level 3: 35%-60%
NEET - 2022
Hints

advertisementadvertisement

Limiting molar conductivities, for the given solutions, are:

\(\lambda_{m}^{0} \left(\right. H_{2} S O_{4} \left.\right) = x\) \(S  c m^{2}\) \(m o l^{- 1}\)

\(\lambda_{m}^{0} \left(\right. K_{2} S O_{4} \left.\right) = y\) \(S  c m^{2}\) \(m o l^{- 1}\)

\(\lambda_{m}^{0} \left(\right. C H_{3} C O O K \left.\right) = z\) \(S  c m^{2}\) \(m o l^{- 1}\)

From the data given above, it can be concluded that \(\lambda_m^0 \) in (\(S\ cm^2\ mol^{-1}\)) for CH3COOH will be:

1. \(\mathrm{x-y+2z}\) 2. \(\mathrm{x+y+z}\)
3. \(\mathrm{x-y+z}\) 4. \(\mathrm{{(x-y) \over 2}+z}\)
Subtopic:  Conductance & Conductivity |
 69%
Level 2: 60%+
NEET - 2019
Hints
Links

The molar conductivity of a 0.5 mol/dm3 solution of AgNO3 with electrolytic conductivity of 5.76 × 10–3 S cm1 at 298 K is:

1. 11.5 S cm2/mol 2. 21.5 S cm2/mol
3. 31.5 S cm2/mol 4. 41.5 S cm2/mol
Subtopic:  Conductance & Conductivity |
 88%
Level 1: 80%+
NEET - 2016
Hints
Links

The correct expression that  represents the equivalent conductance at infinite dilution of Al2(SO4)3 is:

(Given that Al3+° and SO42-° are the equivalent conductances at infinite dilution of the respective ions)

1. Al3+° + SO42-°

2. Al3+° + SO42-°×6

3. 13Al3+° +12 SO42-°

4. 2Al3+° +3 SO42-°

Subtopic:  Conductance & Conductivity |
 64%
Level 2: 60%+
AIPMT - 2010
Hints

advertisementadvertisement