Because of lanthanoid contraction, which of the following pairs of elements have nearly
same atomic radii? (Numbers in the parenthesis are atomic numbers).
1. Ti (22) and Zr (40)
2. Zr (40) and Nb (41)
3. Zr (40) and Hf (72)
4. Zr (40) and Ta (73)
| I: | La(OH)3 is least basic among hydroxides of lanthanides. |
| II: | Zr4+ and Hf4+ possess almost the same ionic radii. |
| III: | Ce4+ can act as an oxidising agent. |
Which of the following elements generally exhibit multiple oxidation states and form coloured ions in aqueous solution?
1. Metalloids
2. Transition elements
3. Non-metals
4. Noble gases
A colored ion in aqueous solutions among the following is:
1. La3+ (Z=57)
2. Ti3+ (Z=22)
3. Lu3+ (Z=71)
4. Sc3+ (Z=21)
Which of the following statements correctly describes lanthanoids?
| 1. | 14 elements in the seventh period (atomic no. = 90 to 103) that are filling 5f sublevel. |
| 2. | 14 elements in the sixth period (atomic no. 58 to 71) that are filling 4f sublevel |
| 3. | 14 elements in the seventh period (atomic no. = 58 to 71) that are filling 4f sublevel |
| 4. | 14 elements in the sixth period (atomic no. 90 to 103) that are filling 4f sublevel |
Identify the incorrect statement among the following:
| 1. | There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu. |
| 2. | Lanthanoid contraction is the accumulation of successive shrinkages |
| 3. | As a result of lanthanoid contraction, the properties of the 4d series of the transition elements have no similarities with the 5d series of elements |
| 4. | The shielding power of 4f electrons is quite weak. |
| Statement I: | Actinoid contraction is greater from element to element than lanthanoid contraction. |
| Statement II: | 5f orbitals have a poorer shielding effect than 4f orbitals. |
| 1. | Statement I is True and Statement II is False. |
| 2. | Statement I is False and Statement II is True. |
| 3. | Both Statement I and Statement II are False. |
| 4. | Both Statement I and Statement II are True. |
| 1. | The greater metallic character of the lanthanoids than that of the corresponding actinoids. |
| 2. | More energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
| 3. | The lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
| 4. | More active nature of the actinoids. |