The hybridisation of [FeF6]3- is:

1. sp3d2 2. d2sp3
3. dsp3 4. sp3
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The compound with the highest magnetic moment value is:

1. \( {\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}} \)
2. \( {\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}} \)
3. \({\left[\mathrm{Zn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}} \)
4. \( {\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}}\)

Subtopic:  VBT, CFT & their Limitations |
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The difference between a weak field ligand and a strong field ligand is:

1. Weak field ligands cause higher splitting in the d orbitals than strong field ligands.
2. Weak field ligands cause lower splitting in the d orbitals than strong field ligands.
3. Strong field ligands do not form a complex with a metal ion.
4. None of the above.

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The crystal field splitting energy is:

1. The heat of formation between the two levels (e and t2) in tetrahedral splitting
2. The total pairing energy of the two levels (e and t2) in tetrahedral splitting.
3. The sum of the energy levels in an octahedral crystal field splitting.
4. The combined energy of the two levels (eg and t2g) in octahedral splitting.

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[Cr(NH3)6]3+ is paramagnetic ,while Ni(CN)42- is diamagnetic because:

1. Electrons in the 3d orbitals remain unpaired in Ni(CN)42-
2. Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+
3. Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+
4. Electrons in the 3p orbitals remain unpaired in Ni(CN)42-

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The greater value of the stability constant of complex salt indicates:

1. The greater proportion of products.

2. The greater proportion of reactants

3. Lesser concentration of catalyst at equilibrium

4. All of the above

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The correct order for the wavelengths of absorption in the visible region for the following is:
\(\left[\mathrm{Ni}\left(\mathrm{NO}_2\right)_6\right]^{4-},\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+},\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
1. [Ni(H2O)6]2+ < [Ni(NH3)6]2+ < [Ni(NO2)6]4-

2. [Ni(H2O)6]2+ > [Ni(NH3)6]2+ > [Ni(NO2)6]4-

3. [Ni(NH3)6]2+ > [Ni(H2O)6]2+> [Ni(NO2)6]4-

4.  [Ni(H2O)6]2+ > [Ni(NO2)6]4-> [Ni(NH3)6]2+

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The number of unpaired electrons in the following complexes respectively are-

K4[Mn(CN)6],Fe(H2O)6]2+,K2[MnCl4]

1. 1, 4, 5

2. 2, 4, 5

3. 0, 3, 4

4. 2, 3, 4

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The correct splitting diagram of d orbitals in an octahedral crystal field is:

1. 2.
3. 4.  
None of the above
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