For the reaction, the plot of log k vs is given below :
Find the temperature(K) at which the rate constant of the reaction is 10–4s–1 ?
(Rounded-off to the nearest integer)
[Given: The rate constant of the reaction is
| 1. | 546 K | 2. | 536 K |
| 3. | 516 K | 4. | 526 K |
The rate constant of a reaction increases by five times on increase in temperature from 27°C to 52°C. The value of activation energy in kJ mol–1 is-
(Rounded-off to the nearest integer) [R = 8.314 J K–1 mol–1]
1. 50
2. 56
3. 52
4. 60
The rate constant (k) of a reaction is measured at different temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol–1 is:
(R is gas constant)
1. 2R
2. R
3. 1/R
4. 2/R
The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ ) of the reaction is:
(Take R=8.314 J and In 3.555=1.268)
1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol
Two reactions, R1 and R2 have identical pre-exponential factors. Activation energy of R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2 respectively at 300 K, then ln(k2/k1) is equal to:
(R = 8.314 J mol–1 K–1).
1. 6
2. 4
3. 8
4. 12
Which of the following statements is correct regarding the equation k = Ae-Ea/RT ?
1. k is the equilibrium constant
2. A is adsorption factor
3. Ea is the energy of activation
4. R is the Rydberg constant
| 1. | 1 | 2. | 5 |
| 3. | 2 | 4. | 8 |
Consider the equilibrium reaction: A(g) ⇌ B(g) with an enthalpy change (ΔH) of -42 kJ/mol.
Determine the activation energies for the forward and backward reactions, given that the ratio of the activation energy of the forward reaction to the activation energy of the backward reaction is 2 : 3.
| 1. | 84 kJ/mole, 126 kJ/mole | 2. | 24 kJ/mole, 36 kJ/mole |
| 3. | 48 kJ/mole, 72 kJ/mole | 4. | 90 kJ/mole, 135 kJ/mole |