At 1990 K and 1 atm pressure, there are an equal number of Cl2 molecules and Cl atoms in the reaction mixture.
The value of KP for the reaction Cl2(g)2Cl(g) under the above conditions is x × 10–1. The value of x is:

1. 4

2. 8

3. 5

4. 10

Subtopic:  Introduction To Equilibrium |
 59%
Level 3: 35%-60%
JEE
Please attempt this question first.
Hints
Please attempt this question first.

For the reaction A(g)(B)(g), the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of rG for the reaction at 300 K and 1 atm in J mol–1 is – xR, where x is:
(R = 8.31 J mol–1 K–1 and ln 10 = 2.3)

1. 1400

2. 1380

3. 1360

4. 1340

Subtopic:  Introduction To Equilibrium |
 86%
Level 1: 80%+
JEE
Please attempt this question first.
Hints
Please attempt this question first.

For a reaction; X+Y2Z, 1.0 mol of X, 1.5 mol of Y and 0.5 mol of Z were taken in a 1 L vessel and allowed to react. At equilibrium, the concentration of Z was 1.0 mol L–1 . The equilibrium constant of the reaction is x15. The value of x is:

1. 24

2. 13

3. 16

4. 19

Subtopic:  Introduction To Equilibrium |
 80%
Level 1: 80%+
JEE
Please attempt this question first.
Hints
Please attempt this question first.

advertisementadvertisement

Given that the equilibrium constant (KC) at 800 K for the reaction \(N_2(𝑔)+3H_2(𝑔)⇋2NH_3(𝑔)\) is 64. What is the equilibrium constant Kat the same temperature for the reaction \(NH_3(g) ⇌ \dfrac{1}{2}N_2(g) + \dfrac{3}{2}H_2(g)\)?

1.  \(\dfrac{1}{4}\) 2. \(\dfrac{1}{8}\)
3. 8 4. \(\dfrac{1}{64}\)
Subtopic:  Introduction To Equilibrium |
 88%
Level 1: 80%+
Please attempt this question first.
Hints
Please attempt this question first.

For the following reactions, equilibrium constants are given below:

S(s) + O2(g) SO2(g); K1 = 1052

2S(s) + 3O2(g) 2SO3(g); K2 = 10129

The equilibrium constant for the reaction, 2SO2(g) + O2(g) 2SO3(g) is:

1. 10154 2. 10181
3. 1025 4. 1077
Subtopic:  Introduction To Equilibrium |
 80%
Level 1: 80%+
JEE
Please attempt this question first.
Hints
Please attempt this question first.

The equilibrium constant at 298 K for a reaction A + B  C + D is 100.
If the initial concentration of all the four species were 1 M each, then equilibrium concentration of D (in mol L–1) will be :

1. 0.182 2. 0.818
3. 1.818 4. 1.182
Subtopic:  Introduction To Equilibrium |
 67%
Level 2: 60%+
Please attempt this question first.
Hints
Please attempt this question first.

advertisementadvertisement

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the COis converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

1. 1.8 atm

2. 3 atm

3. 0.3 atm

4. 0.18 atm

Subtopic:  Introduction To Equilibrium |
 66%
Level 2: 60%+
Please attempt this question first.
Hints
Please attempt this question first.

In a closed reaction vessel, Phosphorus pentachloride dissociates as follows:

\(\mathrm{PCl}_{5}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)\)

If the total pressure at equilibrium of the reaction mixture is P and the degree of dissociation of PCl5  is x, the partial pressure of PCl3 will be:

1. \(\left(\frac{x}{x+1}\right) P\)

2. \(\left(\frac{2x}{x-1}\right) P\)

3. \(\left(\frac{x}{x-1}\right) P\)

4.  \(\left(\frac{x}{1-x}\right) P\)

Subtopic:  Introduction To Equilibrium |
 73%
Level 2: 60%+
JEE
Please attempt this question first.
Hints
Please attempt this question first.

Consider the reaction equilibrium :  \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) ; \quad \Delta H^{\circ}=-198 \mathrm{~kJ} \)

On the basis of Le-Chatelier's principle, the condition favorable for the forward reaction is : 

1. lowering of temperature as well as pressure 

2. increasing temperature as well as pressure 

3. lowering the temperature and increasing the pressure 

4. Any value of temperature and pressure 

Subtopic:  Introduction To Equilibrium |
 83%
Level 1: 80%+
JEE
Please attempt this question first.
Hints
Please attempt this question first.

advertisementadvertisement

For the gaseous equilibrium reaction:
\({N_2O_4 (g) \rightleftharpoons 2NO_2 (g)}\), the equilibrium concentrations of \(\mathrm{N_2O_4}\) and \(\mathrm{NO_2}\)​ are \(4.8 \times 10^{-2}\) and \(1.2 \times 10^{-2}\), respectively.

Calculate the value of the equilibrium constant \(K_c\)​ for the reaction:

1. 3.3 \(\times\) 10mol L-1
2. 3 \(\times\) 10-1  mol L-1
3. 3 \(\times\) 10-3  mol L-1
4. 3 \(\times\) 10mol L-1

Subtopic:  Introduction To Equilibrium |
 88%
Level 1: 80%+
Please attempt this question first.
Hints
Please attempt this question first.