The correct order of increasing energy of atomic orbital is:
1. 3s, 3p, 4s, 3d, 4p
2. 3s, 3p, 3d, 4s, 4p
3. 3s, 3p, 4s, 4p, 3d
4. 3s, 3p, 3d, 4p, 4s
The de-Broglie wavelength of a particle having the momentum of
3.3 x 10-24 kg m s-1 will be;
1. 0.002 Å
2. 0.02 Å
3. 0.2 Å
4. 2Å
The maximum number of atomic orbitals associated with a principal quantum number 5 is-
1. 9
2. 12
3. 16
4. 25
The first line in the Lyman series in the spectrum of hydrogen atom occurs at a wavelength of 1215 Å and the limit for Balmer series is 3645 Å. Calculate the wavelength corresponding to series limit of Lyman series.
1. 911.2 Å
2. 812.2 Å
3. 712.2 Å
4. 678.4 Å
In Rutherford's alpha scattering experiment using gold foil, the kinetic energy of the alpha particle was 1.2 x 10-12J. For a head on collision, using the formula K.E. = x 2Ze2/r0 , what may be the magnitude of r0 [ The nuclear radius of gold, Z=79; = 9 x 109 new-ton/meter2 coulomb-2, e= 1.6x10-19 coulomb]
1. 3 x 10-14m
2. 1.3 x 10-14m
3. 2.1 x 10-14m
4. 4.3 x 10-14m
If uncertainty in the position of an electron is zero the uncertainty in its momentum will be:
1. <h/4
2. >h/4
3. zero
4. infinite
Which of the following statements is not true with respect to photoelectric effect -
1. The plot of kinetic energy of the photoelectrons against frequency of absorbed radiation gives a straight line parallel to x-axis
2. The plot of K.E. of the photoelectrons against frequency of absorbed radiation gives a straight line with slope equal to h and intercept to work function of metal
3. The plot of kinetic energy of the photoelectrons versus the intensity of incident radiation with constant frequency gives a straight line parallel to x-axis
4. When intensity of light is increased the number of photons ejected increases but the energies of these electrons are the same.
Velocity of helium atom at 300 K is 2.40 x 102 meter per sec. What is its wavelength? (mass number of helium is 4) -
1. 0.416 nm
2. 0.83 nm
3. 803 Å
4. 8000 Å
The de Broglie wavelength of electron of He+ ion is 3.329Å. If the photon emitted upon de-excitation of this He+ ion is made to hit H atom in its ground state so as to liberate electron from it, what will be the de Broglie's wavelength of photoelectron ?
1. 0.1518 Å
2. 6.1518 Å
3. 2.3518 Å
4. 4.1218 Å
An absorption line of the lowest frequency in the transition of hydrogen spectra is:
1. n=1 to n=2
2. n=3 to n=8
3. n=2 to n=1
4. n=8 to n=3