The final product C in the below mentioned reaction is:
\(\xrightarrow[]{Ac_2O}\ A\ \xrightarrow[CH_3COOH]{Br_2}\ B\ \xrightarrow[H^+]{H_2O}\ C\)
\(\xrightarrow[]{Ac_2O}\ A\ \xrightarrow[CH_3COOH]{Br_2}\ B\ \xrightarrow[H^+]{H_2O}\ C\)
1. | 2. | ||
3. | 4. |
Match the reactions given in Column-I with the statements given in Column-II.
Column-I | Column-II | ||
A. | Ammonolysis | (i) | Amine with a lesser number of carbon atoms |
B. | Gabriel phthalimide synthesis | (ii) | Detection test for primary amines. |
C. | Hofmann bromamide reaction | (iii) | Reaction of phthalimide with KOH and R—X |
D. | Carbylamine reaction | (iv) | Reaction of alkyl halides with NH3 |
Codes:
A | B | C | D | |
1. | (ii) | (iii) | (iv) | (i) |
2. | (iii) | (i) | (iv) | (ii) |
3. | (i) | (iv) | (iii) | (ii) |
4. | (iv) | (iii) | (i) | (ii) |
1. | Acetic anhydride in pyridine. |
2. | A mixture of nitric acid and sulphuric acid at low temperatures. |
3. | Conc. sulphuric acid followed by heating at 200°C. |
4. | Conc. nitric acid at high temperature. |
Assertion (A): | Anilinium hydrogen sulphate, on heating, forms meta-aminobenzene sulfonic acid. |
Reason (R): | The sulfonic acid group is an electron-donating group. |
1. | Both (A) and (R) are true, and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is a true statement but (R) is false. |
4. | Both (A) and (R) are false statements. |