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The pH of a 0.045 M solution of the monoprotic acid is 5.30. What is the Ka of monoprotic acid?

(Given: 10-5.30 = \(5.0 \times 10^{-6}\))

1. 1.1 × 10-4
2. 5.0 × 10-6
3. 2.0 × 10-9
4. 5.6 × 10-10
Subtopic:  Ionisation Constant of Acid, Base & Salt |
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What is the pH of a solution obtained by mixing 50 mL of water with 50 mL of a 1×10-3 M barium hydroxide solution?

1. 3.0

2. 3.3

3. 11.0

4. 11.7

Subtopic:  pH calculation |
 59%
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Consider the following statements:

I. Ionic product of water KW cannot change with temperature. 
II. The value of the equilibrium constant is independent of the initial concentration of the reactant and products.
III. The equilibrium constant for an exothermic reaction decreases as the temperature increases. 


Which of the above statements is true?

1. I and II only

2. I and III only

3. II and III only

4. I, II, and III

Subtopic:  Introduction To Equilibrium |
 82%
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For the reaction, A(g2B(g⇌ 3CKc 102. If at equilibrium one mole of A is added and 1 mole of C is removed then, the value of Kc will be: 

1. 102 2. 103
3. 104 4. 10
Subtopic:  Introduction To Equilibrium |
 83%
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What is the correct equilibrium expression for the given reaction?
Cu(OH)2(s) + 4 NH3(aq) \(\leftrightharpoons\) Cu(NH3)42+(aq) + 2 OH¯(aq)
1. Keq \(\dfrac{[Cu(NH_3)_4^{2+}][OH^-]}{[NH_3]}\)
2. Keq  = \(\dfrac{[Cu(NH_3)_4^{2+}][2~OH^-]}{[4~NH_3]}\)
3. Keq  = \(\dfrac{[Cu(NH_3)_4^{2+}][OH^-]^2}{[NH_3]^4}\)
4. Keq \(\dfrac{[Cu(NH_3)_4^{2+}][2~OH^-]^2}{[4~NH_3]^4}\)
Subtopic:  Kp, Kc & Factors Affecting them |
 91%
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A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of  NH4 is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8×10–5, then what is the pH of this solution? 
(log 1.8 = 0.25; log 0.67 = –0.176)

1.  9.43
2.  11.72
3.  8.73
4.  9.08

Subtopic:  Buffer |
 66%
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An aqueous solution of NaOH has a concentration of 0.01 mol/L.
Calculate the pH of the NaOH solution at 25 °C.

Given the ionic product of water is Kw = [H+] [OH] = 10–14 mol2/L2 (at 25 °C)
1.  11

2.  7

3.  14

4.  12

Subtopic:  pH calculation |
 83%
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The solubility of \(Sr(OH)_2 \) at 298 K is 20 g/L of solution. The pH of this solution will be:
 
(Given: molar mass of Sr = 88 g/mol; log 40 =1.60 ; and log 122 = 2.086)
1. 13.51 
2. 0.48 
3. 10.22 
4. 11.25 
Subtopic:  Solubility Product |
 76%
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For the reaction, 
\(H_2NCOONH_4 (s) \rightleftharpoons2 NH_3(g) + CO_2(g)\), the total pressure at equilibrium is 15 atmospheres. It can be concluded that the value of \(K_P\) will be:
1. 15 atm3
2.  50 atm3 
3.  500 atm3
4.  100 atm3
Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction, 

\(N_2(g) + 3H_2 (g) \rightleftharpoons 2NH_3(g) \), on adding inert gas at constant volume, equilibrium: 
 
1. shifts in the forward reaction 
2. shifts in backward reaction 
3. remains unaffected 
4. Initially in the forward direction and then in the backward direction
Subtopic:  Le Chatelier's principle |
 85%
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