The half-cell reaction at the anode during the electrolysis of aqueous sodium chloride solution is represented by :
1. Na+(aq) + e- ⟶ Na(s) ; \(E_{cell}^{o} \ = \ -2.71 \ V \)
2. 2H2O(l) ⟶ O2(g) + 4H+(aq) + 4e- ; \(E_{cell}^{o} \) = 1.23 V
3. H+(aq) + e- ⟶ \(\frac{1}{2}\)H2(g) ; \(E_{cell}^{o} \) = 0.00 V
4. Cl-(aq) ⟶ \(\frac{1}{2}\)Cl2(g) + e- ; \(E_{cell}^{o}\)
1. | weight of cathode increases |
2. | pH of the solution remains unchanged |
3. | product at the anode is \(O_2\) gas |
4. | weight of the anode is unchanged |
During the electrolysis of a highly concentrated H2SO4 solution, which is released at the anode?
1. H2
2. O2
3. S2O82–
4. Both (1) & (3)