The rate constant for a reaction 2×10–2 s–1 at 300 K and 8×10–2 s–1 at 340 K. The energy of activation of the reaction is:
1. 14.69 kJ mol–1
2. 29.39 kJ mol–1
3. 44.34 kJ mol–1
4. 22.05 kJ mol–1
For a reaction, activation energy and the rate constant at 200 K is 1.6 . The rate constant at 400K will be [Given that gas constant, R=8.314 J ]
1. 3.2 × 104 s-1
2. 1.6 × 106s-1
3. 1.6 × 103 s-1
4. 3.2 × 106 s-1
When the temperature of a reaction increases from 300 K to 310 K, the rate of the reaction doubles. What is the activation energy for this reaction?
\((R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \text { and } \log 2=0.301)\)
1. | \(53.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) | 2. | \(68.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) |
3. | \(59.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \) | 4. | \(70.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\) |
If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by:
1. t = 2.303/k
2. t = 0.693/k
3. t = 6.909/k
4. t = 4.606/k
If 60% of a first-order reaction was completed in 60 min, 50% of the same reaction would be completed in approximately:
(log 4 = 0.60, log 5 = 0.69)
1. | 50 min | 2. | 45 min |
3. | 60 min | 4. | 40 min |
In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:
1. Rate = k[A][B]2
2. Rate = k[A]2[B]2
3. Rate = k[A][B]
4. Rate = k[A]2[B]
The rate constant of the given reaction-
R(g) \(\xrightarrow[]{\Delta }\) 2P(g) is 2.48 × 10–4 s–1.
A 1 : 1 molar ratio of R to P in the reaction mixture is attained after:
1. 32 min
2. 27.3 min
3. 20 min
4. 0 min
For a zero-order reaction, the initial amount of reaction is 20 g and half-life is 30 minutes. The amount of reactant left after 60 minutes would be:
1. 5 g
2. 10 g
3. 2.5 g
4. Zero
The rate constant of a reaction is
3 x 10-3 mol-2 L2s-1. Hence, the order is:
1. 1
2. Zero
3. 2
4. 3
A reaction having equal energies of activation for forward and reverse reaction has:
1. ΔG = 0
2. ΔH = 0
3. ΔH = ΔG = ΔS = 0
4. ΔS = 0