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For the reaction, 

\(N_2(g) + 3H_2 (g) \rightleftharpoons 2NH_3(g) \), on adding inert gas at constant volume, equilibrium: 
 
1. shifts in the forward reaction 
2. shifts in backward reaction 
3. remains unaffected 
4. Initially in the forward direction and then in the backward direction

Subtopic:  Le Chatelier's principle |
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For the reaction, 
\(H_2NCOONH_4 (s) \rightleftharpoons2 NH_3(g) + CO_2(g)\), the total pressure at equilibrium is 15 atmospheres. It can be concluded that the value of \(K_P\) will be:
1. 15 atm3
2.  50 atm3 
3.  500 atm3
4.  100 atm3
Subtopic:  Kp, Kc & Factors Affecting them |
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Given below are two statements:
Assertion (A): If Qp<Kp reaction moves in the direction of reactants.
Reason (R): The reaction quotient is defined in the same way as the equilibrium constant at any stage of the reaction.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Introduction To Equilibrium |
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Initially 2 moles of \(NOCl \) taken in 1 L of closed container and it dissociates into NO and Cl2 gas.
The reaction is as follows:
\(2 \mathrm{NOCl}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Cl}_2(g)\)
Calculate the equilibrium constant Kc given that 0.4 moles of NO is obtained at equilibrium.
1. 142 × 10-4 2. 142 × 10-6
3. 125 × 10-4 4. 130 × 104
Subtopic:  Introduction To Equilibrium |
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A weak acid is titrated with a weak base. Consider the following statements regarding the pH of the solution at the equivalence point:
(i) pH depends on the concentration of acid and base.
(ii) pH is independent of the concentration of acid and base.
(iii) pH depends on pKa of acid and pKb of base.
(iv) pH is independent of pKa of acid and pKb of base.
The correct statements are :
1. only (i) and (iii) 2. only (i) and (iv)
3. only (ii) and (iii) 4. only (ii) and (iv)
Subtopic:  pH calculation |
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If 0.01 M acetic acid solution is 1% ionised, then pH of this acetic acid solution is:
1. 3 2. 2
3. 4 4. 1
Subtopic:  pH calculation |
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The solubility of BaSO4 in 10-3 M H2SO 4 solution will be:
(Given: Ksp for BaSO4 = 1.1 × 10-10)
1. 1.1 × 10–13 M 2.  1.1 × 10–7 M
3.  5.5 × 10–7 M 4.  5.5 × 10–8 M
Subtopic:  Solubility Product |
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The solubility of \(Sr(OH)_2 \) at 298 K is 20 g/L of solution. The pH of this solution will be:
 
(Given: molar mass of Sr = 88 g/mol; log 40 =1.60 ; and log 122 = 2.086)
1. 13.51 
2. 0.48 
3. 10.22 
4. 11.25 
Subtopic:  Solubility Product |
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Select the correct order of solubility of AgCl in the following solutions:
(a) \(0.1 \text {M NaCl (aq)} \)
(b) \(0.1~ \text {M} ~\text {CaCl}_2 ~ (\text {aq}) \)
(c) \(0.1~ \text {M} ~\text {AlCl}_3 ~ (\text {aq}) \)
1. (a) = (b) = (c)
2. (a) > (b) > (c)
3. (a) < (b) < (c)
4. (c) > (b) = (a)  
Subtopic:  Common Ion Effect |
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100 ml of \(HCl\) (pH=1) is mixed with 150 ml of \(HCl\) (pH =2). The pH of the resulting solution will be:
(log 4.6 = 0.65)
1. 1.35 
2. 1.5 
3. 1.8 
4. 1.9 
Subtopic:  pH calculation |
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